郑州大学化学与分子工程学院导师：郭丰启 正文

　
　　姓名：郭丰启　　性别：男　　　出生年月：1972年
　　职称：教授　　学院：化学与分子工程学院　最后学历：博士
　　主要研究方向：光与有机小分子、有机金属配合物、共轭高分子材料相互作用后所发生的物理和化学过程

　　郭丰启，博士，教授。1972年2月出生于河南省扶沟县。1995年毕业于北京师范大学化学系，同年考入中科院感光化学研究所（现理化技术研究所）攻读博士学位。2000年6月获得博士学位后，在北京迈劲医药科技有限公司从事化学新药的合成，2001年获得该公司年度优秀员工奖。2002年3月至2004年6月在美国北达科他州立大学(North Dakota State University)孙文芳教授实验室做博士后研究工作，从事聚吡啶铂-芳香炔类配合物的合成及其非线性光学特性的研究。2004年7月 至2006年6月在美国佛罗里达大学(University of Florida) Kirk S. Schanze教授实验室做博士后研究工作。从事水溶性共轭高分子、铂-芳香炔类共轭高分子和低聚物的合成及其在太阳能电池和电致发光方面的应用研究。2006年7月被聘为郑州大学化学系教授，自1998年至今已发表学术论文二十余篇，并有十多篇论文参加国际、国内学术会议交流。

　　研究兴趣：我们小组主要研究光与有机小分子、有机金属配合物、共轭高分子材料相互作用后所发生的物理和化学过程。利用各种光谱技术（例如吸收、荧光、磷光、激光诱导的时间分辨光谱等）揭示光吸收和光发射的机理。利用各种材料的吸收和发射特性来设计合成新型的非线性光学材料、太阳能电池天线分子、光致发光和电致发光材料及荧光探针分子。

　　代表性论文：
　　1. Fengqi Guo, Katsu Ogawa, Young-Gi Kim, Evgeny O. Danilov, Felix N. Castellano, John R. Reynolds and Kirk S. Schanze. “A fulleropyrrolidine end-capped platinum-acetylide triad: the mechanism of photoinduced charge transfer in organometallic photovoltaic cells” , Phys. Chem. Chem. Phys., 2007, 9, 2724.
　　2. Fengqi Guo, Wenfang Sun. "Photophysics and optical limiting of platinum(II) 4'-pyrenylterpyridyl phenylacetylide complexes", J. Phys. Chem. B 2006, 110(30), 15029-15036.
　　3. Fengqi Guo, Young-Gi Kim, John R. Reynolds,* and Kirk S. Schanze*, Solar Cells Based on Blends of a Platinum-Acetylide Polymer with PCBM: Involvement of the Triplet State. Chemical Communication. 2006, 1887
　　4. W. Sun*, F. Guo, "Excited state absorption and optical limiting of platinum(II) 4'-arylterpyridyl acetylide complexes", Chinese Optics Letters, S3, S34 (2005).
　　5. Fengqi Guo, Wenfang Sun, Yao Liu, Kirk Schanze. Synthesis, Photophysics, and optical limiting of platinum(II) 4’-Tolylterpyridyl Arylacetylide complexes. Inorganic Chemistry, 2005, 44, 4055~4065.
　　6. Wenling Jia, Fengqi Guo, Elliot P. Douglas, Wenfang Sun. Optical limiting of semiconductor nanoparticles particles for nanosecond laser pulser. Applied Physics Letters, 2004, 85(26), 6326~6328
　　7. Wenfang Sun*, Fengqi Guo, Dmitri Martyshkin, Sergey Mirov, Chauanlang Zhan, Duoyuan Wang. Wavelength Dispersion of Two-Photon Absorption and Two-Photon Induced Fluorescence of Stilbazolium Derivatives. SPIE, 2003, 5211, 75~81.
　　8. Fengqi Guo, Wenfang Sun, Duoyuan Wang, Lizheng Zhao, Zhenzhong Lu, Yuxin Nie, Optical limiting of pentaazadentate complexes in solution for ps pulses, Applied Optics-LP, 2001, 40 (9), 1386~1388.
　　9. Fengqi Guo, Wenfang Sun, Duoyuan Wang, Yinglin Song, Optical limiting of pentaazadentate complexes in solution for ns pulses, Optical Engineering, 2001, 40 (1), 138~141.
　　10. Fengqi Guo, Wenfang Sun, and Duoyuan Wang. Optical limiting of pentaazadentate metal complexes for ps pulses in solution, Proc. SPIE, 1999, 3798, 58.
　　11. Fengqi Guo, Shiming Dong, and Duoyuan Wang, A novel pentaazadentate bismacrocyclic cadmium complex, Chinese J. Chemistry, 2000, 18 (4), 551
　　12. Fengqi Guo, Quanbo Zhao and Duoyuan Wang, Study of the photofading dynamics of pentaazadentate metal complexes, ACTA CHIMICA SINICA. 2001, 59 (6), 815.
　　13. Fengqi Guo, Wenfang Sun, Yunjing Li, Yinglin Song, Duoyuan Wang, Zhenzhong Lun, Yuxin Nie. “Nonlinear optical properties and optical limiting performances of pentaazadentate metal complexes in solution”, Proc. SPIE, 2000, 4106, 300~310.
　　14. W. Sun, F. Guo, D. Wang, S. Zhang, Z. Xia, Y. Zou. “Optical Kerr effect of pentaazadentate metal complexes”, Chinese Journal of Chemical Physics, 12(5), 543, 1999.
　　15. Fengqi Guo, Wenfang Sun, Xie Jie, Duoyuan Wang. Synthesis of asymmetric pentaazadentate macrocyclic cadmium and indium complexes and the studies of their photophysical properties. Photographic Science and Photochemistry, 1998, 16 (2), 186.
　　16. D. Wang, W. Sun, C. Wang, F. Guo, Y. Zou. Optical limiting behaviors of pentaazadentate metal complexes for nanosecond laser. Proc. SPIE, 1998, 3472, 53
　　17. Fengqi Guo, Duoyuan Wang. Studies of excited-state properties of asymmetric pentaazadentate cadmium and indium complexes. Photographic Science and Photochemistry, 1999, 17 (2), 232.
　　18. Fengqi Guo, Wenfang Sun, and Duoyuan Wang. Optical limiting of pentaazadentate metal complexes for ps pulses in solution, Functional Materials, 2000, 31 (1), 87.
　　19. Fengqi Guo, Duoyuang Wang. Synthesis of asymmetric pentaazadentate macrocyclic indium and lead complexes and their photophysical properties. Hua Xue Tong Bao(Published on internet), 1999(10), 99096.

　　Conference Presentations:
　　1. W. Sun*, F. Guo, W. Jia, E.P. Douglas, Q. Dai, Q. Huo, "Optical limiting of semiconductor nanoparticles and gold nanoparticle/polylysine hybrid materials", to be presented at the Fourth International Symposium on Optical Power Limiting, Dingle, Ireland, July, 2006.
　　2. W. Sun*, F. Guo, H. Zhu, "Photophysics and optical limiting of mononuclear and binuclear platinum(II) 4'-Arylterdentate complexes", presented at the International Symposium on Photonics, Biophotonics, and Nanophotonics'2005 (ISPBN'05), Nanjing, China, May 14-18, 2005.
　　3. W. Sun*, F. Guo, H. Zhu,P.M. Barron, "Photophysics and optical limiting of mononuclear and binuclear platinum(II) terdentate complexes", presented at the Pacifichem 2005 Symposium, Honolulu, Hawaii, Dec. 16, 2005.
　　4. Sun, Wenfang; Guo, Fenqi. Photophysics and optical limiting of platinum(II) 4'-arylterpyridyl phenylacetylide complexes. Abstracts of Papers, 230th ACS National Meeting, Washington, DC, United States, Aug. 28-Sept. 1, 2005 (2005),
　　5. Wenfang Sun and Fengqi Guo. Photophysics and optical limiting properties of platinum(II) 4'-arylterpyridyl arylacetylide complexes; 2004 MRS fall meeting, Boston, USA, Nov.29 ~ Dec.3
　　6. Wenfang Sun, Paul Barron, and Fengqi Guo. Photophysics and optical limiting of pentaazadentate porphyrin-like metal complexes. 2004, Third international conference on porphyrins and phthalocyanines. New Orleans, USA, July11~16.
　　7. W. Sun*, F. Guo, D. Martyshkin, S. Mirov, C.-L. Zhan, D. Wang, "Wavelength dispersion of two-photon absorption and two-photon induced fluorescence of stilbazolium derivatives", presented at 48th SPIE Annual Conference, San Diego, CA, Aug. 3, 2003.
　　8. W. Sun*, F. Guo, "Photophysical properties and optical limiting of platinum (II) 4'-arylterpyridyl arylacetylide complexes", presented at the Third International Symposium on Optical Power Limiting, Sedona, AZ, Sept. 28 - Oct. 2, 2003.
　　9. F. Guo, W. Sun*, "Synthesis, photophysical properties, and optical limiting of 4'-arylterpyridyl acetylide complexes", presented at 4th Biennial North Dakota/South Dakota Joint EPSCoR Conference, Sept. 5, Fargo, ND, 2003.
　　10.P.M. Barron, F. Guo, W. Sun*, "Synthesis and photophysical properties of pentaazadentate porphyrin-like gadolinium (III) complex", presented at 4th Biennial North Dakota/South Dakota Joint EPSCoR Conference, Sept. 5, Fargo, ND, 2003.
　　11.Fengqi Guo, Wenfang Sun*, "Synthesis and spectroscopic studies of platinum (II) terpyridyl arylacetylide complexes", presented at ND EPSCoR 2002 State Conference, Grand Folks, ND, Oct. 26, 2002
　　12.Scott Jason Dee, Fengqi Guo, Wenfang Sun*, "Synthesis and characterization of pentaazadentate porphyrin-like metal complexes for optical limiting applications", presented at 10th Annual North Dakota Undergraduate Research Poster Session, Grand Folks, July 24, 2002
　　13.Paul Barron, Fengqi Guo, Wenfang Sun*, "Synthesis and characterization of pentaazadentate porphyrin-like rare-earth complexes for photodynamic therapy applications", presented at 10th Annual North Dakota Undergraduate Research Poster Session, Grand Folks, July 24, 2002.
　　14.An Young, Fengqi Guo, Wenfang Sun*, "Synthesis and characterization of platinum (II) bipyridyl phenylacetylide complex", presented at 10th Annual North Dakota Undergraduate Research Poster Session, Grand Folks, July 24, 2002.
　　15.Barron, Paul M.; Guo, Fengqi; Sun, Wenfang. Synthesis and characterization of a partially water-soluble pentaazadentate porphyrin-like gadolinium (III) complex for photodynamic therapy application. 227th ACS National Meeting, Anaheim, CA, United State, March 28~April 1, 2004
　　16.Fengqi Guo, Wenfang Sun, Xiejie, Duoyuan Wang. Photophysical properties of pentaazadentate conjugated macrocyclic metal complexes (The fourth Sino-Japan binational symposium on photochemistry).
　　17.Duoyuan Wang, Wenfang Sun, and Fengqi Guo. Optical limiting behaviors of pentaazadentate expanded porphyrin metal complexes for nanosecond pulse laser (The fourth Sino-Japan binational symposium on photochemistry).
 　　18.Guo Feng-qi, Dong Shi-ming, Wang Duo-yuan,“A novel pentaazadentate bismacrocyclic cadmium complex”, (The proceeding of the ninth international symposium on fine chemistry and functional polymers), 1999, Vol.15 (4), 126

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