郑州大学化学与分子工程学院导师：龚军芳 正文

　
　　姓名：龚军芳　　职称：副教授　　
　　学院：化学与分子工程学院　最后学历：博士
　　主要研究方向：金属有机化学和均相催化化学
　　
　　龚军芳，教授、硕士生导师，河南省教育厅学术技术带头人。1992年南开大学化学系毕业；1995年获南开大学理学硕士学位；1998年在中国科学院化学研究所获博士学位。1999.10~2001.09在郑州大学化学系博士后流动站工作；2001.10-2003.2在法国巴黎国家高等化学学校 (Ecole Nationale Superieure de Chimie de Paris) 从事天然产物Ambruticin合成新方法研究。2003年-至今在郑州大学化学系工作。

　　主要从事金属有机化学和均相催化化学研究，先后在Organometallics; Dalton Trans.; Tetrahedron Lett.; J. Mol. Catal. A: Chem.; J. Organomet. Chem.; Aust. J. Chem.等期刊上发表学术论文40余篇 (其中SCI收录论文30余篇)。近年来，主持完成教育部留学回国人员科研启动费、河南省自然科学基金、郑州大学引进人才科研启动费和郑州大学校级青年骨干教师等项目；作为主要人员，参与完成2项国家自然科学基金项目和2项河南省杰出人才创新基金。目前主持国家自然科学基金项目1项。参与翻译、编写著作3部，获专利3项。

　　Email: gongjf@zzu.edu.cn
　　联系地址：河南省郑州市大学北路75号郑州大学化学系 450052

　　近年来主要论文及专利目录：
　　1. Jun-Long Niu, Qing-Tao Chen, Xin-Qi Hao, Qing-Xiang Zhao, Jun-Fang Gong*, Mao-Ping Song*. “Diphenylprolinol-derived Symmetrical and Unsymmetrical Chiral Pincer Pd(II) and Ni(II) complexes: Synthesis via One-pot Phosphorylation/metalation Reaction and C-H Activation.” Organometallics 2010, 29(9), 2148-2156.
　　2. Ben-Shang Zhang, Wei Wang, Dan-Dan Shao, Xin-Qi Hao, Jun-Fang Gong*, Mao-Ping Song*. “Unsymmetrical Chiral PCN Pincer Palladium(II) and Nickel(II) Complexes of (Imidazolinyl)aryl Phosphinite Ligands: Synthesis via Ligand C-H Activation, Crystal Structures and Catalytic Studies.” Organometallics 2010, 29(11), 2579-2587.
　　3. Jun-Fang Gong, Yan-Hui Zhang, Mao-Ping Song*, Chen Xu. “New PCN and PCP Pincer Palladium(II) Complexes: Convenient Synthesis via Facile One-pot Phosphorylation/Palladation Reaction and Structural Characterization.” Organometallics 2007, 26(25), 6487-6492.
　　4. Li-Yuan Wu, Xin-Qi Hao, Yan-Xiao Xu, Min-Qiang Jia, Ya-Nan Wang, Jun-Fang Gong*, Mao-Ping Song*. “Chiral NCN Pincer Pt(II) and Pd(II) Complexes with 1,3-Bis(2'-imidazolinyl)benzene: Synthesis via Direct Metalation, Characterization, and Catalytic Activity in the Friedel-Crafts Alkylation Reaction.” Organometallics 2009, 28(12), 3369-3380.
　　5. Ben-Shang Zhang, Chao Wang, Jun-Fang Gong*, Mao-Ping Song*. “Facile synthesis of achiral and chiral PCN pincer palladium(II) complexes and their application in the Suzuki and copper-free Sonogashira cross-coupling reactions.” J. Organomet. Chem. 2009, 694, 2555-2561.
　　6. Xin-Qi Hao, Ya-Nan Wang, Jun-Rui Liu, Kun-Lun Wang, Jun-Fang Gong,* Mao-Ping Song*. “Unsymmetrical, oxazolinyl-containing achiral and chiral NCN pincer ligand precursors and their complexes with palladium(II).” J. Organomet. Chem. 2010, 695, 82-89.
　　7. Kai Xu, Xin-Qi Hao, Jun-Fang Gong,* Mao-Ping Song,* and Yang-Jie Wu. “Room Temperature Suzuki Reactions in Aqueous Media under Air by Palladium(II) Complexes with Pyrazole Derived Ligands.” Aust. J. Chem. 2010, 63, 315-320.
　　8. Chen Xu, Jun-Fang Gong*, Su-Fang Yue, Yu Zhu, Yang-Jie Wu*. “Tricyclohexylphosphine-cyclopalladated ferrocenylimine complexes: synthesis, crystal structures and application in Suzuki and Heck reactions.” Dalton Trans. 2006, 4730-4739.
　　9. Chen Xu, Jun-Fang Gong*, Tao Guo, Yan-Hui Zhang, Yang-Jie Wu*. “Cyclopalladated ferrocenylimine complexes with dicyclohexylphosphino- biphenyl ligands: Synthesis, crystal structures and their use as highly efficient catalysts for Suzuki reaction of aryl chlorides.” J. Mol. Catal. A: Chem. 2008, 279, 69-76.
　　10. Chen Xu, Jun-Fang Gong*, Yang-Jie Wu*. “Amination of aryl chlorides in water catalyzed by cyclopalladated ferrocenylimine complexes with commercially available monophosphinobiaryl ligands.” Tetrahedron Lett. 2007, 48, 1619-1623.
　　11. Xin-Qi Hao, Jun-Fang Gong*, Chen-Xia Du, Li-Yuan Wu,Yang-Jie Wu, Mao-Ping Song*. “Synthesis, characterization and photoluminescent properties of platinum complexes with novel bis(imidazoline) pincer ligands.” Tetrahedron Lett. 2006, 47, 5033-5036.
　　12. Chen Xu, Jun-Fang Gong*, Yan-Hui Zhang, Yu Zhu, Yang-Jie Wu*. “Synthesis, Characterization and Crystal Structures of Three cis/trans Pyridine- Cyclopalladated Ferrocenylimine Complexes, and Their Catalysis in Suzuki Reactions.” Aust. J. Chem. 2007, 60, 190-195.
　　13. Jun-Fang Gong*, Xin-Heng Fan, Chen Xu, Jin-Lei Li, Yang-Jie Wu*, Mao-Ping Song. “New cycloplatinated complexes with 2-arylimidazolines: synthesis, crystal structures and photophysical properties.” J. Organomet. Chem. 2007, 692, 2006-1013.
　　14. Junfang Gong, Guangyu Liu, Chenxia Du, Yu Zhu, Yangjie Wu*. “Efficient Suzuki coupling of aryl chlorides catalyzed by tricyclohexylphosphine adducts of cyclopalladated ferrocenylimines.” J. Organomet. Chem. 2005, 690(17), 3963-3969.
　　15. Chen Xu, Jun-Fang Gong*, Mao-Ping Song, Yang-Jie Wu*. “Catalysis of the coupling reaction of aryl chlorides with bis(pinacolato)diboron by tricyclohexylphosphine- cyclopalladated ferrocenylimine complexes.” Transition Met. Chem. 2009, 34, 175-179.
　　16. Xin-Qi Hao, Fang Liu, Bi Zhang, Mei-Ling Jiang, Jun-Fang Gong, Mao-Ping Song*. “Cyclopalladated complexes of 2-(m-nitrophenyl)imidazolines: synthesis, characterization and catalytic activity in the Suzuki reaction under mild conditions.” Transition Met. Chem. 2010, 35, 271-277.
　　17. Xin-Qi Hao, Jun-Fang Gong*, Wen-Tao Song, Yang-Jie Wu, Mao-Ping Song*. “Synthesis and crystal structures of mono-, bis- as well as tris-mercurated complexes with ferrocenylazines.” Inorg. Chem. Commun. 2007, 10, 371-375.
　　18. Jun-Fang Gong*, Chen Xu, Yan-Hui Zhang, Yu Zhu, Yang-Jie Wu*. “Synthesis, characterization and crystal structures of two cis/trans pyridine-cyclopalladated ferrocenylimine complexes.” Transit. Metal Chem. 2007, 32, 1000-1004.
　　19. GONG Jun-fang *, ZHANG Yan-hui, FAN Xin-heng, WANG Da-wei, SONG Mao-ping, WU Yang-jie. “Synthesis, Structural Characterization of Ferrocenyl Iminophosphines and Amidophosphines as Well as Their Application in the Suzuki Reaction.” Chem. Res. Chinese U. 2007, 23(6), 683-687.
　　20. Jun-Fang Gong*, Da-Wei Wang, Yan-Hui Zhang, Yu Zhu, Yang-Jie Wu*. “Synthesis and Structural Characterization of Mercury(II) Complexes with a Novel Ferrocenyliminophosphine.” Inorg. Chim. Acta 2006, 359(7), 2115-2120.
　　21. Chen Xu, Jun-Fang Gong, Yan-Hui Zhang, Yu Zhu, Chen-Xia Du, Yang-Jie Wu. “Synthesis, characterization and crystal structures of a novel 1,1’-bisferrocenylimine and its monocyclopalladated derivative.” Inorg. Chem. Commun. 2006, 9, 456-459.
　　22. Ling-Zhi Du, Jun-Fang Gong*, Chen Xu, Yu Zhu, Yang-Jie Wu, Mao-Ping Song*. “Synthesis and structures of novel diastereomeric cyclopalladated ferrocenylimines derived from chiral b-amino alcohols.” Inorg. Chem. Commun. 2006, 9, 410-414.
　　23. Ling-Zhi Du, Jun-Fang Gong*, Yu Zhu, Yang-Jie Wu, Mao-Ping Song*. “Synthesis, characterization and the crystal structures of novel achiral and chiral a-ferrocenyl a-aminophosphine oxides.” Inorg. Chem. Commun. 2006, 9, 529-532.
　　24. Junfang Gong, Guangyu Liu, Yu Zhu, Chenxia Du, Maoping Song, Yangjie Wu*. “Synthesis, Characterization and Catalytic Activity in Suzuki Reaction of Cyclopalladated Ferrocenylimine Tri- phenylphosphine complexes.” Chem. J. Chin. Univ. 2006, 27(7), 1266-1271.
　　25. Junfang Gong, Chen Xu, Yangjie Wu. “Transition-Metal Catalyzed α-Arylation of Carbonyl Derivatives and Compounds with Acidic Hydrogen.” Progress in Chem. 2006, 18(6), 752-760.
　　26. Junfang Gong, Eric Bonfand, Eric Brown, Gilles Dujardin, Véronique Michelet and Jean-Pierre Genêt. “Remarkable stereocontrol in the synthesis of 1,2,3,5-tetrasubstituted tetrahydropyrans via an asymmetric heterocycloaddition of a ketone-derived enol ether. ” Tetrahedron Lett. 2003, 44(10), 2141-2144.
　　27. 龚军芳，吴养洁，徐晨. “环钯化二茂铁亚胺-氨基膦配合物及其应用.” 专利号：ZL 2006 1 0048594.9
　　28. 宋毛平，龚军芳，郝新奇，武利园，汪亚男，吴养洁. “手性和非手性双咪唑啉基苯类化合物及合成方法.” 专利号：ZL 2007 1 0053911.0
　　29. 宋毛平，郝新奇，龚军芳，林昆华，张碧，李玉江. “钳形双咪唑啉钯化合物及其在Suzuki反应中的应用.” 专利号：200710054070.5

　　参与编写、翻译的著作目录：
　　1、现代有机反应 胡跃飞 林国强主编 第五卷《金属催化反应》 撰写《傅-克反应》一章 2008.12 化学工业出版社 ISBN 978-7-122-03784-8
　　2、有机立体化学导论（译著）国外名校名著系列 2007.1 化学工业出版社 ISBN 978-7-5025-8940-0 翻译第13-16章等
　　3、有机化学学习指导 国家理科基地名牌课程建设参考书 2008.1 郑州大学出版社 ISBN 978-7-81106-743-9 参编

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