浙江师范大学化学与生命科学学院导师：吴廷华 正文

　　姓名：吴廷华　
　　性别：男　
　　职称：教授　
　　所在学院：化学与生命科学学院　

　　个人简介：
　　吴廷华，男，理学博士，浙江师范大学生化学院教授。
　　1994.9-1999.6，师从著名物理化学家万惠霖院士攻读博士学位，1999年6月获厦门大学物理化学专业博士学位，同年被评上副教授。2000年创办了浙江师范大学物理化学研究所，时任副所长（万惠霖院士任所长）。2004年晋升教授。2009年获得包玉刚奖学金去美国宾夕法尼亚州立大学做高级访问学者。
　　长期从事低碳烷烃的催化转化、离子液体中精细化学品的合成等方面的研究工作。借助红外、脉冲质谱-色谱在线分析，准原位XPS、1HNMR等手段对POM反应机理的探讨取得了一些成果，提出了POM的热解-氧化机理模型和离子液体催化下铵/胺盐一步法合成季铵盐的催化机理。至2009年12月，申请者已经在国内外著名期刊（Adv. Synth. Catal., Chem. Commun., J. Catal.等）上发表论文80多篇，SCI收录30多篇，其中影响因子4.0以上的3篇。同时还建立了校企合作的实验室，已经把一项科研成果产业化，具有一些产业化的经验。

　　研究领域
　　多相催化与均相催化；
　　绿色催化与精细化学品合成；
　　功能材料的制备。

　　在研（完成）项目（项目负责人）
　　离子液体催化下铵/胺盐一步季铵化反应的研究（56万）（国家自然科学基金）；在研
　　生物质单糖直接合成2、5-二甲基呋喃的新催化反应研究（20万）（浙江省科技厅项目）；在研
　　尿素醇解法制碳酸二甲酯新工艺的研究（28万）（浙江省科技厅项目）；完成
　　烯烃现场过氧环氧化制环氧烷催化反应的研究（10万）（浙江省自然科学基金）；完成
　　尿素醇解法制碳酸二甲酯（25万）（浙江丰登化工）；完成
　　二氧化碳加氢制甲醇催化剂研究（5万）（横向课题）；完成
　　强糠聚合成中试(5万)（横向课题）；完成

　　参与研究项目
　　涉及表面吸附的电化学振荡（国家自然科学基金）；第二
　　非贵金属型低温CO和CH4氧化催化剂研究（浙江省自然科学基金）；第二
　　电化学振荡体系现场拉曼光谱研究与理论模型（浙江省自然科学基金）；第二
　　废水浓缩中试（衢化锦纶厂）。第二
　
　　现（增）开设课程
　　《催化选论》，授课对象:研究生；
　　《催化研究方法》，授课对象:研究生；
　　《物理化学》，授课对象:本科生；
　　《物理化学实验》，授课对象:本科生。

　　已发表论文
　　[1] Zhang, Qi Neng, Zhang, Jing, Wu, Ting Hua, Zhou, Xiao Ping, The oxidation of olefins by t-butyl hydrogen peroxide to prepare 1,2-diols over metal oxide catalysts, Catalysis Communications, 2009, 10(9): 1279-1283.
　　[2] Wu, Ying, Wu, Binfu, He, Yiming, Wu, Tinghua, Direct Conversion of Ethane to Ethylene Oxide over Ni-Ag-O Catalyst, Chemistry Letters, 2009, 38(3): 284-285.
　　[3] Yang, Feng, Liu, Zhen, Li, Wen Sheng, Wu, Ting Hua, Zhou, Xiao Ping, The oxidative bromination of methane over Rh/SiO2 catalyst, Catalysis Letters, 2008, 124(3-4): 226-232.
　　[4] Chen, Fei, Wu, Ting Hua, Zhou, Xiao Ping, The photodegradation of acetone over VOx/MgF2 catalysts, Catalysis Communications, 2008, 9(8): 1698-1703.
　　[5] Wu, Ying, Wu, Binfu, Wu, Tinghua, Influence of the preparation method on the performance of nanostructured Zr-Ni-O catalysts, Reaction Kinetics and Catalysis Letters, 2008, 95(1): 29-37.
　　[6] Z. Q. Zheng, T. H. Wu*, J. Wang, X. P. Zhou, Ionic Liquid Catalyzed Alkylation of Ammonium Salts, Advanced Synthesis & Catalysis, 2007 , 349: 1095-1101.
　　[7] Z. Q. Zheng, T. H. Wu*, X. P. Zhou, The synthesis of quaternary ammonium salts from ammonium salts and dialkyl carbonate, Chem. Commun., 2006, 1864-1865.
　　[8] T. H. Wu*, Q. G. Yan, F. L. Mao, Z. J. Niu, Q. N. Zhang, Z. L. Li, H. L. Wan, Partial oxidation of methane to syngas over Rh/SiO2 catalyst using on-line MS, Catalysis Today, 2004, 93-95: 121-127.
　　[9] T. H. Wu*, Q. G. Yan, H. L. Wan, Partial Oxidation of Methane to Hydrogen and Carbon Monoxide over a Ni/TiO2 Catalyst, Journal of Molecular Catalysis A: Chemical, 2005, 226(1): 41-48.
　　[10] Q. G. Yan, T. H. Wu, W. Z. Weng, H. Toghiani, R. K. Toghiani, H. L. Wan, C. U. Pittman Jr, Partial Oxidation of Methane to H2 and CO over Rh/SiO2 and Ru/SiO2 Catalysts, Journal of Catalysis, 2004, 226(2): 247-259.
　　[11] Z. Q. Zheng, T. H. Wu*, R. W. Zheng, Y. Wu, X. P. Zhou, Study on the synthesis of quaternary ammonium salts using imidazolium ionic liquid as catalyst, Catalysis Communications, 2007, 8(1): 39-42.
　　[12] Y. Wu, Y. M. He, T. H. Wu*, T. Chen, W. Z. Weng, H. L. Wan, Influence of some parameters on the synthesis of nanosized NiO material by modified sol–gel method, Materials Letters, 2007, 61: 3174-3178.
　　[13] Y. Wu, Y. M. He, T. H. Wu*, W. Z. Weng, H. L. Wan, Effect of synthesis method on the physical and catalytic property of nanosized NiO, Materials Letters, 2007, 61: 2679-2682.
　　[14] T. H. Wu*, D. M. Lin, Y. Wu, X. P. Zhou, Q. G. Yan, W. Z. Weng, H. L. Wan, In-situ FTIR investigation partial oxidation of methane to syngas over Rh/SiO2 catalyst, J. Natur. Gas Chem., 2007, 16: 316-321.
　　[15] T. H. Wu*, M. Q. Zhu, Z. J. Niu, Y. J. Zhong, Y. Guan, Y. Liu, Q. G. Yan, Z. L. Li, H. L. Wan, Studies on the Performance and Structure of Supported Catalysts for the Partial Oxidation of Methane to Syngas, Journal of Natural Gas Chemistry, 2002, 11: 159-164.
　　[16] Z. L. Li, T. H. Wu, Z. J. Niu, In situ Ranman spectropic studies on the current oscillations during gold electrodissolution in HCl solution, Electrochem. Commun., 2004, 5 (6) : 44-48.
　　[17] Z. L. Li, Z. J. Niu, T. H. Wu, In situ monitoring of potential oscillations in the reduction of IO3- by electrochemical quartz crystal microbalance, Electrochem. Commun., 2003, 5 (4): 297-300.
　　[18] Q. G. Yan, Z. S. Cao, T. H. Wu, W. Z. Weng, H. L. Wan, Carbon deposition on Ni/Al2O3 Catalyst during Oxidation Of Methane to syngas, Studies in Surface Science And Catalyst, 2000, 130: 3549-3555.
　　[19] Q. G. Yan, Z. Sh. Cao, T. H. Wu, W. Z. Weng, H. L. Wan, Mechanistic Studies of Methane Partial Oxidation to synthesis gas over supported Rhodium Catalyst Studies in Surface Science And Catalysis, Studies in Surface Science And Catalyst, 2000, 130: 3555-3560.
　　[20] Z. S. Cao, Q. G. Yan, T. H. Wu, W. Z. Weng, H. L. Wan, Novel Method of Preparing Zeolite membrans from colloidal zeolite Nay, Studies in Surface Science And Catalyst, 2000, 130: 2897-2903.
　　[21] W. Z. Weng, M. S. Chen, Q. G. Yan, T. H. Wu, H. L. Wan, In-Situ Time-Resolved FTIR Investigation on the Reaction-Mechanism of Partial Oxidation of Methane to Syngas over a SiO2- Supported Rh and Ru Catalysts, CHINESE SCIENCE BULLETIN, 2000, 45(24): 2236-2240.
　　[22] W. Z. Weng, M. S. Chen, Q. G. Yan, T. H. Wu, H. L. Wan, Mechanistic Study of Partial Oxidation of Methane to Synthesis Gas over Supported Rhodium and Ruthenium Catalysts Using in-Situ Time-Resolved FTIR Spectroscopy, Catalysis Today, 2000, (63): 317-326.
　　[23] Y. Wu, Y. M. He, T. H. Wu*, W. Z. Weng, H. L. Wan, Preparation, Characterization and Low Temperature Catalytic Performance of Nanostructured Ti-Ni-O, Surface Science & Review, in press.
　　[24] Q. G. Yan, T. H. Wu, W. Z. Weng, Z. S. Cao, H. L. Wan, Synergism in platinum enhance nickel Catalyst for Oxidation Of Methane to syngas, Journal of Natural Gas Chemistry, 2000, 19(1): 18-31.
　　[25] Q. G. Yan, T. H. Wu, W. Z. Weng, H. L. Wan, Mechanistic Study of Carbon deposition on Catalysts for Oxidation of Methane to syngas, Journal of Natural Gas Chemistry, 2000, 19(1): 89-102.
　　[26] Q. G. Yan, T. H. Wu, W. Z. Weng, H. L. Wan, Mechanistic Study of Methane Partial Oxidation to synthesis gas over supported Rhodium Catalyst, Journal of Natural Gas Chemistry, 2000, 19(1): 1-7.
　　[27] Z. S. Chao, T. H. Wu, J. L. Ye, G. Z. Chen, H. L. Wan, 1H MAS NMR Characterization of Hydrogen over silica-supported medium catalyst, Science in China (Series B), 2001, l44(1): 115-121.
[28] WU Tinghua, YAN Qiangu, ZHANG Qineng, NIU Zhenjiang, CHAO Zisheng, YE Jianliang, WAN Huilin, 1H MAS NMR Study of Partial Oxidation of Methane to Syngas over Rh/SiO2 Catalyst, Chinese Journal of Catalysis, 2004, 25(11): 909-914.
　　[29] WU Tinghua, YAN Qiangu, ZHANG Qineng, MAO Fulin, ZHENG Zhuoqun, CHEN Fei, WENG Weizheng, WAN Huilin, FT-IR Study of Methane Dissocation on Surface of Rh/SiO2 Catalyst, Chinese Journal of Catalysis, 2004, 25(12): 928-930.
　　[30] WU Tinghua, YAN Qiangu, LI Shaobin, ZHONG Yijun, NIU Zhenjiang, ZHU Mingqiao, LI Zhelin, WAN Huilin, Partial Oxidation of Methane to Syngas over Rh/SiO2 Catalyst, Chinese Journal of Catalysis, 2003, 24(6): 407-413.
　　[31] WU Tinghua, YAN Qiangu, LU Wei, NIU Zhenjiang, MAO Fulin, ZHANG Qineng, ZHU Mingqiao, LI Zhelin, ZHONG Yijun, WAN Huilin, Effect of Surface Oxygen Concentration on Actication of Methane over Supported Metal Catalysts, Chinese Journal of Catalysis, 2003, 24(10): 755-759.
　　[32] WU Tinghua, LI Shaobin, YAN Qiangu, Effect of Interaction between Nickel and Alumina on Coke Deposition on Ni/Al2O3 Catalyst for Partial Oxidation of Methane to Syngas, Chinese Journal of Catalysis, 2001, 22(5): 501-504.
　　[33] WU Tinghua, XIA Wensheng, WANG Haiyou, WANG Zhongquan, ZHANG Hongbin, WAN Huilin, CAI Qirui, Reaction Energetics for Water Gas Shift Reaction over the Clean and the Oxygenmodified Cu(100) surfaces—Studied by the Bond Order Conservation Approach, Chinese Journal of Chemical Physics, 1998, 11(1): 69-73.
　　[34] WU Tinghua, LUO Jizhong, ZHU Yimin, WAN Huilin, AFM Study on Binary Rare Earth Oxyfluoride Sm-La-O-F Catalysts, Chinese Journal of Catalysis, 1998, 19(6): 605-607.
　　[35] WU Tinghua, WANG Haiyou, WENG Weizheng, CHENG Mingsu, WAN Huilin, Methane Partial Oxidation to Syngas-A Study of the Nature of Active Site over Rh Based Catalyst, Chinese Journal of Catalysis, 1998, 19(6): 498-501.
　　[36] LI Liangcao, WU Tinghua, HU Dechong, YANG Yuannan, Studies on Correlation between the Physico-Chemical Properties and Molecular Parameters of Alkanes, Chinese Journal of Organic Chemistry, 2003, 23(10): 1125-1130.
　　[37] NIU Zhengjiang, WU Tinghua, LI Zhelin, In situ XRD Investigation on the Crystallization Behaviors of Electroless High-Phosphorous Ni-P Alloys, Acta Physico-Chimica Sinica, 2003, 19(8): 705-708.
　　[38] MAO Fu-lin, WU Tinghua*, LIU Ya, GUANG Yan, ZHENG Zhuo-qun, ZHANG Qi-neng, CHENG Fei, Study on the Synthesis of Methyl Carbamate through Alcoholysis of Urea, Natural Gas Chemical Industry, 2005, 30(1): 14-16.
　　[39] ZHENG Zhuo-qun, WU Tinghua*, MAO Fu-lin, ZHANG Qi-neng, CHEN Fei, Thermodynamic Analysis of Methyl Carbamate Synthesis from Urea and Methanol, Natural Gas Chemical Industry, 2004, 29(5): 72-73.
　　[40] MAO Fulin, WU Tinghua, DAI Chunhua, ZHENG Zhuoqun, ZHANG Qineng, CHENG Fei, Analysis of the synthesis of methyl carbamate from urea and methanol by reversed phase high performance liquid chromatography, Chinese Journal of Analysis Laboratory, 2005, 24(8): 85-87.
　　[41] MAO Fulin, WU Tinghua, LIU Ya, ZHENG Zhuoqun, ZHANG Qineng, CHENG Fei, On the synthesis of methyl carbamate through alcoholysis of urea, Journal of Zhejiang Normal University (Natural Sciences), 2005, 28(1): 54-56.
　　[42] ZHENG Zhuoqun, WU Tinghua, MAO Fulin, ZHANG Qineng, CHENG Fei, Thermodynamic Analysis of the Synthesis of Dimethyl Carbonate from Methyl Carbamate and Methanol, Chemical Engineering of Oil and Gas, 2005, 34(2): 87-89.
　　[43] NIU Zhengjiang, NI Yahong, LI Zhelin, WU Tinghua, DU Xiaoguang, Influence of zinc ion on electrochemically synthesis of polyaniline, Journal of Zhejiang Normal University (Natural Sciences), 2005, 28(1): 47-50.
　　[44] LIU Ya, WU Tinghua, MAO Fulin, GUAN Yan, ZHU Mingqiao, Preliminary Studies on the Synthesis of Dimethyl Carbonate by Methyl Carbamate Alcoholysis, GUIZHOU CHEMICAL INDUSTRY, 2005, 30(1): 23-26.
　　[45] DU Xiaoguang, NIU Zhengjiang, LI Zhelin, WU Tinghua, Effects of electrodeposition conditions on the texture of methanesulfonate tin deposits, Electroplating & Finishing, 2004, 23(5): 6-9.
　　[46] DU Xiaoguang, NIU Zhengjiang, YING Taokai, WU Tinghua, LI Zhelin, Effect of Octyl Polyethylene Glycol Phenyl Ether on the Textures of Tin Electrodeposited from Methanesulfonic Acid Baths, Plating & Finishing, 2004, 26(2): 1-4.
　　[47] NIU Zhengjiang, YV Ping, WANG Feihua, LI Zhelin, WU Tinghua, Effects of citric acid on electroless Ni-P alloy deposition rate and properties, Electroplating & Finishing, 2003, 22(5): 23-26.
　　[48] NIU Zhengjiang, SHI Zhongxiang, LI Zhelin, WU Tinghua, Effects of Surfactants on the Texture and Morphology of Tin Coating, ELECTROPLATING & POLLUTION CONTROL, 2003, 23(5): 8-10.
　　[49] ZHU Mingqiao, WU Tinghua, XIE Fangyou, New progress in catalysts for preparation of methanol, Modern Chemical Industry, 2003, 23(3): 18-21.
　　[50] NIU Zhengjiang, WU Tinghua, YANG Fangzu, YAO Shibing, ZHOU Saomin, Electrocatalytic Activity of Electrodeposited Amorphous Fe-Mo Alloy for Hydrogen Evolution Reaction in Alkaline Solution, Materials Protection, 2003, 36(8): 9-12.
　　[51] NIU Zhengjiang, SHEN Jijun, LI Zhelin, WU Tinghua, In Situ XRD Investigation on Structure Change of Electroless Ni-P Alloys, Materials Protection, 2003, 36(70): 45-47.
　　[52] LI Saobin, WU Tinghua, Effect of preparation methods on the catalysts for catalytic preformance the Partial Oxidation of Methane (POM) to Syngas, JOURNAL OF NINGDE TEACHERS COLLEGE(NATURAL SCIENCE), 2002, 14(4): 302-305.
　　[53] ZHU Mingqiao, XIE Fangyou, WU Tinghua, Application of Green Chemistry and Technology in Chemical Industry, Chemical Production and Technology, 2002, 9(4): 27-32.
　　[54] LIN Rui, ZHONG Yijun, WU Tinghua, LUO Mengfei, LIU Weiping, Characterization and Preparation of Ce-Sn-O Complex Oxides, Journal of the Chinese Society of Rare Earths, 2002, 20(3): 203-206.
　　[55] NIU Zhengjiang, WU Jie, WU Tinghua, YAO Shibing, ZHOU Saomin, Study of solderable lead free tin-bismuth alloy electrodeposition, Electroplating & Finishing, 2002, 21(3): 1-5.
　　[56] LI Saobin, WU Tinghua, WANG Xiaoxing, DU Jingxing, HE Yimin, MA Li, HU Xiaochun, Synthesis of urea formaldehyde resin—Using NaOH to adjust pH value,Journal of Zhejiang Normal University (Natural Sciences), 2001, 24(3): 260-264.
　　[57] LI Saobin, WU Tinghua, HE Yimin, DU Jingxing, MIAO Jigeng, A New Synthesis of Urea Formaldehyde Resin, Journal of Quanzhou Normal University, 2001, 19(2): 31-34.
　　[58] Li Shaobin, WU Tinghua, Lin Hong, Fang Yanyun, The Study on Preparation of Syngas Catalysts Ni- Cu/r-Al2O3 and Its Capability, Journal of Nanping Teachers College, 2001, 20(2): 61-64.
　　[59] LI Saobin, WU Tinghua, YV Guojun, ZHAO Hong, Investigation of the Partial Oxidation of Methane (POM) to Syngas over Cu Modified Ni-based Catalyst, JOURNAL OF NINGDE TEACHERS COLLEGE (NATURAL SCIENCE), 2001, 13(4): 313-316.
　　[60] CAO Zisheng, LIN Haiqiang, CHEN Guozhou, WU Tinghua, WAN Huilin, MIN Enze, Synthesis of Ultrafine Zeolite NaY(Ⅰ)—Effect of Light Rare Earth Ions Additive, CHEMICAL JOURNAL　OF CHINESE UNIVERSITIES, 2000, 21(9): 1353-1358.
　　[61] WU Tinghua, YAN Qiangu, WAN Huilin, Partial Oxidation of Methane to Syngas over Nickel-based Perovskite-like Mixed Oxide Catalysts, Journal of Zhejiang Normal University (Natural Sciences), 1999, 22(2): 55-59.
　　[62] YAN Qiangu, LI Jitao, WU Tinghua, WENG Weizheng, WAN Huilin, Effects of supports on partial oxidation of methane to syngas, Natural Gas Chemical Industry, 1999, 24(3): 4-8.
　　[63] WU Tinghua, CHEN Zhong, Application High Resolution Solid State NMR in the Studies of Heterogeneous Catalysis, Journal of Zhejiang Normal University (Natural Sciences), 1998, 21(2): 41-47。

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