姓名：郝二宏
性别：男
出生年月：
职称：教授
学院：化学与材料科学学院
研究方向：

所受教育
1996．9-2000．8，山东大学化学系, 本科；
2000．9-2003．8，中国科学技术大学化学系，硕士，导师：王官武教授；
2003．8-2007．12，美国路易斯安娜州立大学化学系，博士，导师：Graca Vicente 教授。

职称职位
2008 年 1 月 –现在: 安徽师范大学化学与材料科学院，安徽师范大学引进“双十”人才

主持项目
“新型四氮配体金属催化剂的设计合成及性能研究”（国家自然科学基金项目，2010-2012，主持)
“新型金属corrole衍生物合成及催化性能研究”（教育部留学回国人员基金项目，2010-2012，主持）
“新型近红外光敏剂的合成与性能研究”（教育部博士点新教师基金 2010-2012，主持）
“卟啉烯衍生物的全合成与性能研究”（安徽省教育厅重点项目，2009-2011，主持）
“金属卟啉自组装超分子体系的设计合成及其对三聚氰胺类分子的识别性能研究” (安徽自然科学基金，2009-2011，主持)
“新型4-氮配体的设计合成及催化性能研究”（安徽师范大学“双十”人才启动基金，2008-2011，主持）

研究领域
有机合成
有机功能材料设计
多氮配体催化剂分子设计

讲授课程
有机化学
综合化学实验

获奖情况
2002年 中国科学技术大学光华奖学金
2005年 Colgate-Palmolive and LSU Chemistry Department Award for Excellence in Research
2006-2008年 LSU Charles Coates Research Award
2006-2007年 LSU Graduate School Dissertation Fellowship
007-2008年 LSU Charles Coates Outstanding Dissertation Award

发表论文
Fabre, B.; Hao, E. H.; LeJeune, Z. M.; Amuhaya, E. K.; Barriere, F.; Garno, J. C.; Vicente, M. G. H. Polythiophenes Containing In-Chain Cobaltabisdicarbollide Centers. ACS Appl. Mater. Interfaces ASAP, DOI: 10.1021/am9007424.
Hao, E. H.; Wang, Z. Y.; Jiao, L. J.; Wang, S. W.; “Click” Tetradentate Ligands. Dalton Trans. 2010, 39, 2660-2666.
Hao, E. H.; Jensen, T. J.; Vicente, M. G. H. Synthesis of porphyrin-carbohydrate conjugates using “click” chemistry and their preliminary evaluation in human HEp2 cells. J. Porphyrins Phthalocyanines 2009, 13, 51-55.
Jiao, L. J.; Yu, C. J.; Li, J. L.; Wang, Z. Y.; Wu, M.; Hao, E. H. β-FormylBODIPYs from Vilsmeyer-Haack Reaction. J. Org. Chem.2009, 74, 7525-7528.
Barriere, F.; Fabre, B.; Hao, E. H; LeJeune, Z. M.; Hwang, E.; Garno, G. C.; Nesterov, E. E.; Vicente, M. G. H. Electropolymerizable 2,2′-Carboranyldithiophenes. StructureProperty Investigations of the Corresponding Conducting Polymer Films by Electrochemistry, UVVisible Spectroscopy and Conducting Probe Atomic Force Microscopy. Macromolecules 2009, 42, 2981-2987.
Hao, E. H.; Friso, E.; Miotto, G.; Jori, G.; Soncin, M.; Fabris, C.; Sibrian-Vazquez, M.; Vicente, M. G. H. Synthesis and biological investigations of tetrakis(p-carboranylthio–tetra fluorophenyl) chlorine (TPFC). Organic & Biomolecular Chemistry 2008, 6, 3732-3740.
Hao, E. H.; Zhang, M.; Wenbo, E., Kadish, K. M.; Fronczek, F. R.; Courtney, B. H.; Vicente, M. G. H. Synthesis and Spectroelectrochemistry of N-Cobaltacarborane Porphyrin Conjugates. Bioconjugate Chemistry 2008, 19, 2171-2181.
Soncin, M.; Friso, E.; Jori, G.; Hao, E. H.; Vicente, M. G. H.; Miotto, G.; Colautti, P.; Moro, D.; Esposito, J.; Rossi, G.; Fabris, C. Tumor-localizing and radiosensitizing properties of meso-tetra(4-nido-carboranylphenyl)porphyrin (H2TCP). Journal of Porphyrins and Phthalocyanines 2008, 12, 866-875.
Hao, E. H; Fabre, B.; Fronczek, F. R.; Vicente, M. G. H. Syntheses and Electropolymerization of Carboranyl-Functionalized Pyrroles and Thiophenes. Chemistry of Materials. 2007, 19, 6195-6205.
Hao, E. H; Fabre, B.; Fronczek, F. R.; Vicente, M. G. H. Carborane-embedded polythiophenes: New thermally resistant conducting polymers. Chemical Communications. 2007, 4387-4389.
Hao, E. H.; Sibrian-Vazquez, M.; Fronczek, F. R.; Garno, J.; Vicente, M. G. H. Syntheses, Aggregation and Cellular studies of Porphyrin-cobaltacarborane Conjugates. Chemistry, a European Journal, 2007, 32, 9035-9042.
Fabris, C.; Vicente, M. G. H.; Hao, E. H.; Friso, E.; Borsetto, L.; Jori, G.; Miotto, G.; Colautti, P.; Moro, D.; Esposito, J.; Ferretti, A.; Rossi, C. R.; and Soncin, M. Tumour-localizing and -photosensitising Properties of Meso-tetra(4-nido-carboranylphenyl)porphyrin (H2TCP). Journal of Photochemistry & Photobiology, B: Biology. 2007, 89, 131-138.
Jiao, L. J.; Hao, E. H.; Vicente, M. G. H.; Smith, K. M. An Improved Syntheses of 5,5’-Diformyl-2,2’-Bipyrrole. Journal of Organic Chemistry, 2007, 72, 8119-8122.
Jiao, L. J.; Hao, E. H.; Fronczek, F. R.; Vicente, M. G. H.; Smith, K. M. Syntheses of Functionalized Oxacalix[4]arene Porphyrins. Tetrahedron 2007, 63, 4011-4017.
Hao, E. H.; Fronczek, F. R.; Vicente, M. G. H. Carboranylated Pyrroles and Porphyrins via the Suzuki Cross-Coupling Reaction. Chemical Communications 2006, 4900-4902.
Hao, E. H.; Fronczek, F. R.; Vicente, M. G. H. Synthesis of Oxacalixarene-Locked Bisporphyrins and Higher Oligomers. Journal of Organic Chemistry 2006, 71, 1233-1236.
Jiao, L.; Hao, E. H.; Fronczek, F. R.; Vicente, M. G. H.; Smith, K. M. Benzoporphyrins via Olefin Ring-Closure Metathesis Methodology. Chemical Communications 2006, 3900-3902.
Sibrian-Vazquez, M.; Hao, E. H.; Jenson, T.; Vicente, M. G. H. Enhanced Cellular Uptake with a Cobaltacarborane-Porphyrin-HIV-1 Tat 48-60 Conjugate. Bioconjugate Chemistry 2006, 17, 928-934.
Hao, E. H.; Vicente, M. G. H., Expeditious Synthesis of Porphyrin-Cobaltacarborane Conjugates. Chemical Communications 2005, 1306-1308.
Hao, E. H.; Jensen, T. J.; Courtney, B. H.; Vicente, M. G. H., Synthesis and Cellular Studies of Porphyrin-Cobaltacarborane Conjugates. Bioconjugate Chemistry 2005, 16, 1495-1502.
Wang, G. W.; Jiao, L. J.; Hao, E. H.; Lu, Y. M.; Yang, Y. J., Aggregation Properties of an Amphiphilic Methanofullerene Derivative in THF-H2O Solvent Mixtures. Chinese Chemical Letters 2004, 15, (5), 579-582.
Wang, G. W.; Hao, E. H.; Jiao, L. J.; Yan, L. F., Investigation of Solvatochromism and Aggregation Behavior of C60(C4H10N+)I- in Binary Solvent Mixtures. Chinese Science Bulletin 2003, 48, (18), 1938-1942.
Wang, G. W.; Zhang, T. H.; Hao, E. H.; Jiao, L. J.; Murata, Y.; Komatsu, K., Solvent-Free Reactions of Fullerenes and N-alkylglycines with and without Aldehydes under High-Speed Vibration Milling. Tetrahedron 2003, 59, (1), 55-60.

会议报告
Hao, E. H.; Jiao, L. J.; Fronczek, F. R.; Smith, K. M., Vicente, M. G. H. Oxacalixarene-linked porphyrins and their analogs. Org-357, Abstracts of papers, 233rd American Chemical Society, Chicago, IL 2007.
Hao, E. H. and Vicente M. G. H. Syntheses and Characterization of Boronated Porphyrins for Application in BNCT of Cancer. Oral 26, 4th Euroboron, Bremen (Germany), September 2007.
Luguya, R.; Hao, E. H.; Vicente M. G. H.; Smith, K. M. Synthesis of Boronatedhlorins for the Combined PDT and BNCT of Tumors. Oral 48, 4th Euroboron, Bremen (Germany), September 2007.
LeJeune, Z. M.; McKenzie, M.; Daniels, S. L.; Hao, E. H.; Chen, B.; Vicente, J M. G. H.; Garno, C. Controlling the Organization of Porphyrins on Surfaces using Nanolithography. Poster presented at The National FACSS meeting in Memphis, October 2007.
Serem, W. K.; Hao, E. H.; Daniels, S. L.; Fronczek, F. R.; Vicente, M. G. H.; Garno. J. C. Progressive stages of the crystal growth of porphyrin-cobaltcarborane conjugates captured by AFM. Poster presented at The National FACSS meeting in Memphis, October 2007.
Zhang, M.; Wenbo, E., Hao, E. H. Vicente, M. G. H.; Kadish, K. Electrochemistry and Spectroelectrochemistry of free-base Porphyrin-linked Bis(dicarbollyl) cobalt(III) Conjugates. Abstracts of Papers, 62rd American Chemical Society Southwest regional Meeting, Houston, Tx. 2006, INOR-582.
Hao, E. H.; Vicente. M. G. H. Synthesis and Properties of Porphyrin-cobaltacarborane Conjugates. Oral #288, 4rd International Conference on Porphyrins and Phthalocyanines, Rome (Italy), July 2006. Published in Journal of Porphyrins and Phthalocyanines 2006, 10, 288.
Hao, E. H. Fabre, B.; Vicente, M. G. H.; Synthesis and Electrochemistry of Carborane-containing Pyrroles and Thiophenes. Oral INOR-160, 62th Southwest Regional Meeting of the American Chemical Society, Houston (TX), October 2006.
ao, E. H.; Vicente, M. G. H. “Synthesis of Porphyrin-metallacarborane Conjugates.” Poster #682, 3rd International Conference on Porphyrins and Phthalocyanines, New Orleans (LA), July 2004. Published in Journal of Porphyrins and Phthalocyanines 2004, 8, 682.

专 利

Vicente, M. G. H.; Hao, E. H. Boron-Containing Porphyrin Compounds, Their Use in Boron Neutron Capture Therapy, Photodynamic Therapy and Other Uses. PCT. Int. Appl. WO 2006-US41396, 2007.
*如果发现导师信息存在错误或者偏差，欢迎随时与我们联系，以便进行更新完善。 联系方式